Search results for "lcsh:Chemical technology"
showing 10 items of 291 documents
9,10-Phenanthrenedione as Visible-Light Photoredox Catalyst: A Green Methodology for the Functionalization of 3,4-Dihydro-1,4-Benzoxazin-2- Ones thro…
2018
A visible-light photoredox functionalization of 3,4-dihydro-1,4-benzoxazin-2-ones through a Friedel-Crafts reaction with indoles using an inexpensive organophotoredox catalyst is described. The reaction uses a dual catalytic system that is formed by a photocatalyst simple and cheap, 9,10-phenanthrenedione, and a Lewis acid, Zn(OTf)2. 5W white LEDs are used as visible-light source and oxygen from air as a terminal oxidant, obtaining the corresponding products with good yields. The reaction can be extended to other electron-rich arenes. Our methodology represents one of the most valuable and sustainable approach for the functionalization of 3,4-dihydro-1,4-benzoxazin-2-ones, as compared to th…
Intercomparison of Soil Moisture Retrieved from GNSS-R and from Passive L-Band Radiometry at the Valencia Anchor Station
2019
In this paper, the SOMOSTA (Soil Moisture Monitoring Station) experiment on the intercomparison of soil moisture monitoring from Global Navigation Satellite System Reflectometry (GNSS-R) signals and passive L-band microwave radiometer observations at the Valencia Anchor Station is introduced. The GNSS-R instrument has an up-looking antenna for receiving direct signals from satellites, and a dual-pol down-looking antenna for receiving LHCP (left-hand circular polarization) and RHCP (right-hand circular polarization) reflected signals from the soil surface. Data were collected from the three different antennas through the two channels of Oceanpal GNSS-R receiver and, in addition, calibration …
Automotive Radar in a UAV to Assess Earth Surface Processes and Land Responses
2020
The use of unmanned aerial vehicles (UAVs) in earth science research has drastically increased during the last decade. The reason being innumerable advantages to detecting and monitoring various environmental processes before and after certain events such as rain, wind, flood, etc. or to assess the current status of specific landforms such as gullies, rills, or ravines. The UAV equipped sensors are a key part to success. Besides commonly used sensors such as cameras, radar sensors are another possibility. They are less known for this application, but already well established in research. A vast number of research projects use professional radars, but they are expensive and difficult to hand…
Multi-Crop Green LAI Estimation with a New Simple Sentinel-2 LAI Index (SeLI)
2019
The spatial quantification of green leaf area index (LAIgreen), the total green photosynthetically active leaf area per ground area, is a crucial biophysical variable for agroecosystem monitoring. The Sentinel-2 mission is with (1) a temporal resolution lower than a week, (2) a spatial resolution of up to 10 m, and (3) narrow bands in the red and red-edge region, a highly promising mission for agricultural monitoring. The aim of this work is to define an easy implementable LAIgreen index for the Sentinel-2 mission. Two large and independent multi-crop datasets of in situ collected LAIgreen measurements were used. Commonly used LAIgreen indices applied on the Sentinel-2 10 m ×
Vibration Monitoring of the Mechanical Harvesting of Citrus to Improve Fruit Detachment Efficiency
2019
The introduction of a mechanical harvesting process for oranges can contribute to enhancing farm profitability and reducing labour dependency. The objective of this work is to determine the spread of the vibration in citrus tree canopies to establish recommendations to reach high values of fruit detachment efficiency and eliminate the need for subsequent hand-harvesting processes. Field tests were carried out with a lateral tractor-drawn canopy shaker on four commercial plots of sweet oranges. Canopy vibration during the harvesting process was measured with a set of triaxial accelerometer sensors with a datalogger placed on 90 bearing branches. Monitoring of the vibration process, fruit pro…
Cuticular Wax Composition of Wild and Cultivated Northern Berries
2020
The outer-most layer of plant surface, the cuticle, consists of epi- and intra-cuticular wax. It protects the plant from dehydration, extreme temperatures and UV radiation, as well as attacks from pests such as molds and bacteria. Berry cuticular waxes are studied to understand the metabolism character (factors affecting wax layer composition in different berry species) and increase the microbial resistance and shelf life of berries. The aim of this study was analysis of the surface wax composition of nine species of wild and cultivated berries from Northern Europe. Cuticular wax analysis were done using gas chromatography-mass spectrometry. A total of 59 different compounds were identified…
Effect of Sunlight Exposure on Anthocyanin and Non-Anthocyanin Phenolic Levels in Pomegranate Juices by High Resolution Mass Spectrometry Approach
2020
Quali-quantitative analyses of anthocyanins and non-anthocyanin phenolic compounds performed with the use of liquid chromatography coupled with high resolution mass spectrometry, were evaluated in juice of pomegranate fruits (&lsquo
Highly-Efficient Release of Ferulic Acid from Agro-Industrial By-Products via Enzymatic Hydrolysis with Cellulose-Degrading Enzymes: Part I–The Super…
2021
Historically Triticum aestívum L. and Secale cereále L. are widely used in the production of bakery products. From the total volume of grain cultivated, roughly 85% is used for the manufacturing of flour, while the remaining part is discarded or utilized rather inefficiently. The limited value attached to bran is associated with their structural complexity, i.e., the presence of cellulose, hemicellulose, and lignin, which makes this material suitable mostly as a feed supplement, while in food production its use presents a challenge. To valorize these materials to food and pharmaceutical applications, additional pre-treatment is required. In the present study, an effective, sustainable, and …
Bridging the Knowledge Gap for the Impact of Non-Thermal Processing on Proteins and Amino Acids
2019
Proteins represent one of the major food components that contribute to a wide range of biophysical functions and dictate the nutritional, sensorial, and shelf-life of food products. Different non-thermal processing technologies (e.g., irradiation, ultrasound, cold plasma, pulsed electric field, and high-pressure treatments) can affect the structure of proteins, and thus their solubility as well as their functional properties. The exposure of hydrophobic groups, unfolding followed by aggregation at high non-thermal treatment intensities, and the formation of new bonds have been reported to promote the modification of structural and functional properties of proteins. Several studies reported …
Relationship between seed morphological traits and ash and mineral distribution along the kernel using debranning in durum wheats from different geog…
2020
Debranning was applied to durum wheat to the study the relationship between kernel shape and size, and ash and mineral distribution having implications for semolina yield. To this aim four durum wheat genotypes carried out over three environments were selected to determine the morphological and yield traits as well as the distribution along the kernel of the ash, macro- (Na, K, P, Ca, and Mg), and micro-elements (Mn, Fe, Cu, Zn, and Mo). A descendent ash gradient within the kernel reflects the decreases in the minerals that occurred during debranning. Perciasacchi with high seed weight (TKW) and greater thickness followed by Cappelli showed a more uniform distribution of ash content along t…